Cuprotect
Cuprotect™ is not a paint, but is a complete hull protection
system utilising copper and copper alloys which effectively inhibit
bio-fouling and eliminates the need for toxic antifouling paints.
In addition to its unique anti-fouling properties, by forming an impermeable
seal between the boat hull and the water, Cuprotect™ protects
the hull from degradation caused by osmosis in GRP, rust in steel
and rot and marine infestation in wood. Due to its non-conductive
properties, Cuprotect™ also offers protection against galvanic
action and degradation caused by electrolysis - without the need for
sacrificial anodes and provides many years of guaranteed durability
with little or virtually no maintenance.
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| Any type of boat can be fitted with Cuprotect™ |
Cuprotect™ utilises the known metallurgical performance of copper
and its alloys in an ingenious combination of several bonded layers
of material which are very durable, highly effective in preventing
fouling and environmentally friendly, as Cuprotect™ contains
no organotins, synthetic biocides or volatile organic compounds (VOC's).
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| Magnified picture of Cuprotect™Illustrating total coverage
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The first layer, known as the primer layer, consists of an extremely
strong bonding coat of epoxy resin which is readily applied by either
roller or spray to the many varieties of substrates that can be
treated. This primer layer provides a very stable and durable base
for the remaining components of the Cuprotect™ system.
The next layer also uses epoxy resin and is known as the binder
coat. This layer incorporates carefully chosen thixotropic agents
which provide the correct environment to support the final 'exposed'
layer of the Cuprotect™ system, while simultaneously forming
a very tough and durable bond to the primer layer.
The final outer layer consists of granular copper alloy which is
bonded into the surface of the binder coat. It is this outer layer
that is freely exposed to water, that provides Cuprotect™
with its unique anti-fouling properties.
A LIFETIME SUBMERGED
Any structure that is destined to spend all of its life submerged
in water needs to be fit for purpose. If the water is pure and free
from animal, vegetable and mineral additives and contaminants, then
manufacturers of working and pleasure vessels could happily specify
a selection of modern materials.
The facts are, however, that both fresh and salt-water environments
are far from pure and have their own respective characteristics.
In fresh water such as canals, navigable rivers and reservoirs,
algae and weed tend to become attached to the underside of vessels,
particularly if they are relatively static in their applications.
In sea-water environments many different varieties of micro organisms
exist which, together with molluscs, such as barnacles, form the
familiar build-up of fouling. This is observed at its extreme on
the permanently submerged pillars of piers where often the original
structure cannot be seen for the sheer volume of attached growth.
THE ANNUAL SCRUB BECOMES UNNECCESSARY
For owners of pleasure craft built in GRP, fibreglass being the
popular, practical and economic material from which to construct
strong hulls for vessels, the traditional protection against bio-fouling
has been the annual application of specialised paints to freshly
scrubbed hulls.
Regular re-application is necessary because these paints are designed
to wear away when in contact with water making the attachment of
bio-fouling difficult to sustain. Early versions contained materials
toxic to marine life, however legislation in recent years has restricted
the ingredients of such paints to less harmful compounds.
A more eco-friendly solution with minimal maintenance, eliminating
the need for this annual lift-scrub-and-paint procedure, is now
commercially available courtesy of a novel innovation from the company
Ecosea.
Copper sheets were used centuries ago to ‘skin’ some
of the earliest wooden naval craft, protecting against bio-fouling
and also attack by marine borers. Ecosea have homed in on the exceptional
and unique properties of one of its alloys, copper-nickel.
At a ratio of 90/10 this alloy displays the optimum resistance
to bio-fouling in all water systems, requiring no replacement, usually
for the life of the product it protects. In most cases any routine
inspection required can be readily performed without lifting.
In the case of fibre-glass hulls and other structures, a matrix
of small platelets of the alloy are applied to the underwater areas
as self-adhesive sheets approximately 30cm x 36cm, each with enough
flexibility to be shaped to the substrate, forming a comprehensive
and continuous cladding. Flatter areas can accept plain sheets of
copper-nickel (see illustration ). Any small gaps between the platelets
and sheets are subsequently filled with a grouting epoxy, which
is ‘sqweegeed’ over the fine joints and the excess simply
wiped off.
Cuproguard™ is not only suitable for cladding to GRP, it can
be used just as easily and effectively on wood, aluminium and steel,
hulls and structures.
The performance of the 90/10 alloy as a protective cladding is well
established as a result of many years of testing on both pleasure
and commercial craft with an amazing success record. Experiments
on yachts, ferries, piers and static structures, have shown that
bio-fouling control can be simple and effective using copper-nickel.
In some cases entire hulls have been constructed in the alloy. The
very thin, complex oxide skin that forms when the copper-nickel
is submerged gently dissuades attachments in an ecologically compatible
manner. After long static exposure a light slime will form, itself
containing bio-material. Macro-fouling may occasionally try to colonise
too, but will slide off readily, either with natural water movement,
or alternatively with a light wipe to clear the surface. Now, with
the availability of the product from Ecosea, benefiting from the
properties of copper-nickel can be simply achieved via a simple
post operation to most new or existing hulls and underwater structures.

RESEARCH & TEST RESULTS
HSE Approval
HSE Approval - HSE 8062
Significant research followed by numerous trials have been conducted
on Copper Nickel alloys to confirm the suitability of the material
and product for marine use. Before Cuprotect™ could be licensed
for use it was necessary to conduct stringent independent trials
to ascertain the safety, efficacy and durability of the product.
One such trial was conducted by the UK Government Centre for Environment,
Fisheries & Aquaculture Sciences(CEFAS). Six anti-fouling paints
(considered to be the most effective anti-foul paints on the market)
were compared by CEFAS against Cuprotect™. The tests conducted
were to satisfy ISO/DIS 15181-2 to determine the amount of copper
and biocide release.
As Cuprotect™ contains no biocides other than oxide film formation
it is consequently considered to be very clean. The CEFAS report
clearly identifies Cuprotect™ as the most durable and environmentally
friendly form of anti-fouling available in the world today.
CEFAS: The Centre for Environment, Fisheries & Aquaculture Sciences
(Burnham on Sea) Laboratory, Essex.
Tests were conducted by CEFAS to satisfy the strict controls and
regulations laid down by government.Six antifouling paints (considered
to be the most effective products on the market) were sent to CEFAS
along with Cuproguard™ (tile adhesive version of Cuprotect™)
The tests were carried out to satisfy ISO/DIS 15181-2. This determines
the amount of copper based release. ISO/DIS 15181-1 determines other
biocide release. Cuprotect™ contains no biocides other than
oxide film formation, and it's clean. The CEFAS report clearly identifies
Cuprotect™ as the most durable and environmentally friendly
anti-fouling available in the world today.
SEA TRIALS:
The objective of sea trails was to compare our own practical test
results with the CEFAS report at the time of publication. Five test
sites were selected for their differing types of seawater, Liverpool
Marina, Holyhead Harbour, Fal River, Isle of Scilly and the River
Humber.
Liverpool Marina: Quiet, clean mix of fresh and seawater.
Holyhead Harbour: Tidal exposed coastal seawater.
River Fal: Tidal river with some agricultural run-off and pollution.
Isle of Scilly: Archipelago with very clean unpolluted seawaters.
River Humber: Tidal River with some industrial and agricultural
pollution.
The test sites were examined after 6 and 7 months, one test buoy
in the river Fal was lost. The test buoys showed differing rates
of marine fouling on competitor products, only two products were
completely free from any growth. The CEFAS report confirmed the
actual sea trial results. After 12 months Cuprotect™ was the
only sample free of fouling.
RIGOROUS ADHESIVE TESTING:
The tests for Cuprotect™ using our own epoxies are conclusive.
In all tests carried out the bond strength of the epoxy adhesive
is greater than that of both the cohesive and tensile strengths
of GRP/FRP and Concrete. Testing can be carried out on other substrates
by request.
These tests apply to Cuproguard™ and Cuprotect™ and
are now completed:Shear tests, Tensile tests, Extreme Climatic Conditions
(Thermal Shock) tests, Impermeability tests using hydraulic pressure
and vacuum tests.
HOW CUPROTECT™ WORKS
Cuprotect™, which is not a paint, is best described as a combination
of copper alloys, engineered to conform to the compound curvatures
of hulls of sea going yachts and ships, marine structures, under-water
pipelines, sea water intakes and indeed, anything that is submerged
in water and liaible to bio-fouling.
Cuprotect™ utilises the metallurgical performance of copper
alloys in an ingenious combination of several bonded layers that
make it easy to apply, very durable, very effective and extremely
friendly to the environment as the Cuprotect™ system does
not contain any organotins such as TBT's, or volatile organic compounds
(VOC's).
The Cuprotect™ system is approximately 350 microns thick and
made of granular copper alloys which are bonded into a 'binder coat'
of epoxy resin, that contains specially formulated thixotropic agents
to ensure a strong and uniform finish. This binder coat is applied
to a primer coat of epoxy resin which seals and protects the hull
by forming an inpermeable seal.

The unique patented Cuprotect™ system is applied by approved
installers only, using specialised computer controlled spray equipment,
developed exclusively for Ecosea. This allows application onto compound
curved surfaces, such as boat hulls, and by creating an impermeable
seal, Cuprotect™also drastically reduces the possibility of
osmosis. rust and corrosion.
There is a long, well documented history that confirms the excellent
anti-fouling performance and durability of this outstanding alloy.
This is mainly due to its durability created by the tough copper
nickel oxide film that is formed within hours of immersion and fully
matures after 3-4 months. It is this thin but tough Copper Nickel
Oxide film that gives Cuprotect™ such a long life expectancy
- and a guarantee of 5 years!
Cuprotect™is virtually non-corrodible in clean seawater i.e.
natural corrosion is from 1-2 microns per year and even in polluted
waters only between 2-12 microns per year, making it perfect as
a long term bio-fouling solution not only for yachts and ships,
but also to protect offshore platforms, sea water inlets and condensers
and underwater pipe work.
When used on the hull of a boat Cuprotect™ becomes active
within a period of twelve hours after launching and gains full protection
by three months, offering protection for many years against fouling,
osmosis, rust and general hull degradation.
PROTECTING AGAINST OSMOSIS/HYDROLYSIS
Yachts are a huge investment in both time and money. The resale
value of a yacht with evidence of osmosis can be reduced by at least
30% or as much as 50%, that's if you can find a buyer willing to
take it on! Even after professional and expensive osmosis treatment
by a competent yard there's no absolute guarantee that it will not
reappear. There's only one sure way to prevent osmosis and that
is to keep water/water vapour away from the gel coat.
There are many causes of osmosis in boats built in Glass Reinforced
Polyester (GRP). The main causes are poor workmanship, bad practice,
inferior materials and a general disregard or lack of quality control.
All materials used in boat building, particularly those used in
the hull need to be of the highest quality. All these hull materials
are a compromise and all require maintenance, nothing is maintenance
free. Wooden hulls can rot and become infested by marine borers.
Steel hulls will eventually rust and corrode away. Ferro Cement
hulls can and do suffer from internal degradation caused by rusting
strengtheners and mesh. But with GRP hulls the major worry is osmosis,
although this doesn't normally cause structural problems it's a
financial catastrophe.
The osmosis defence offered by Cuprotect™ is formidable.
The barrier of defence consists of a totally impermeable epoxy resin
primer coat. a secondary binder coat and a final layer of granulated
copper alloy. The complete matrix has been pressure tested to 15
atmospheres, 220 psi, forcing water and air through the matrix.
Cuprotect™ was not breached, even under these destructive
tests.
There is simply no better protection or defence against osmosis/hydrolysis
than that of Cuprotect™ anywhere in the world.
SAFE TO THE ENVIRONMENT
As a responsible manufacturer and provider of environmentally friendly
products, systems and services, we at ECOSEA treat the environmental
issues earnestly. The company is therefore absolutely committed
to the best environmental practices and policies.
There are huge benefits to the environment by using Cuprotect™,
compared to polluting anti-fouling paints. Unlike some pain products
which contain copper particals suspended within the paint matrix,
Cuprotect™ is a solid, engineered product which has 100% active
surface open to the marine environment, thereby Cuprotect™does
not need regular abrasion to expose the active ingredients.
The cuprous oxide film that develops on Cuprotect™after immersion,
not only provides an inhospitable surface to fouling organisms,
but effectively seals the Cuprotect™ thereby ensuring leech
rates stay significantly below any other copper based products.
The U.K. government expressed a great deal of interest in the development
of Cuprotect™ and its predecessor, Cuproguard™, not
least due to the potential environmental benefits. After a close
examination of the project, by independent experts, U.K. govenment
approval was given for full grant aid in November 2000.
Cuprotect™ is the only anti foul product currently available
on the market which is safe to the environment yet still very effective
at preventing marine bio fouling, as it does not contain any organotins
such as TBT, nor volatile organic compounds (VOC's) such as solvents,
both of which are found in great quantities in anti-foul paints
and both of which are extremely damaging, not only to marine life
but also to the ozone layer.
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