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Cuprotect


Cuprotect™ is not a paint, but is a complete hull protection system utilising copper and copper alloys which effectively inhibit bio-fouling and eliminates the need for toxic antifouling paints. In addition to its unique anti-fouling properties, by forming an impermeable seal between the boat hull and the water, Cuprotect™ protects the hull from degradation caused by osmosis in GRP, rust in steel and rot and marine infestation in wood. Due to its non-conductive properties, Cuprotect™ also offers protection against galvanic action and degradation caused by electrolysis - without the need for sacrificial anodes and provides many years of guaranteed durability with little or virtually no maintenance.

Any type of boat can be fitted with Cuprotect™

Cuprotect™ utilises the known metallurgical performance of copper and its alloys in an ingenious combination of several bonded layers of material which are very durable, highly effective in preventing fouling and environmentally friendly, as Cuprotect™ contains no organotins, synthetic biocides or volatile organic compounds (VOC's).

Magnified picture of Cuprotect™Illustrating total coverage


The first layer, known as the primer layer, consists of an extremely strong bonding coat of epoxy resin which is readily applied by either roller or spray to the many varieties of substrates that can be treated. This primer layer provides a very stable and durable base for the remaining components of the Cuprotect™ system.
The next layer also uses epoxy resin and is known as the binder coat. This layer incorporates carefully chosen thixotropic agents which provide the correct environment to support the final 'exposed' layer of the Cuprotect™ system, while simultaneously forming a very tough and durable bond to the primer layer.
The final outer layer consists of granular copper alloy which is bonded into the surface of the binder coat. It is this outer layer that is freely exposed to water, that provides Cuprotect™ with its unique anti-fouling properties.

   

A LIFETIME SUBMERGED
Any structure that is destined to spend all of its life submerged in water needs to be fit for purpose. If the water is pure and free from animal, vegetable and mineral additives and contaminants, then manufacturers of working and pleasure vessels could happily specify a selection of modern materials.

The facts are, however, that both fresh and salt-water environments are far from pure and have their own respective characteristics. In fresh water such as canals, navigable rivers and reservoirs, algae and weed tend to become attached to the underside of vessels, particularly if they are relatively static in their applications.

In sea-water environments many different varieties of micro organisms exist which, together with molluscs, such as barnacles, form the familiar build-up of fouling. This is observed at its extreme on the permanently submerged pillars of piers where often the original structure cannot be seen for the sheer volume of attached growth.

THE ANNUAL SCRUB BECOMES UNNECCESSARY
For owners of pleasure craft built in GRP, fibreglass being the popular, practical and economic material from which to construct strong hulls for vessels, the traditional protection against bio-fouling has been the annual application of specialised paints to freshly scrubbed hulls.

Regular re-application is necessary because these paints are designed to wear away when in contact with water making the attachment of bio-fouling difficult to sustain. Early versions contained materials toxic to marine life, however legislation in recent years has restricted the ingredients of such paints to less harmful compounds.
A more eco-friendly solution with minimal maintenance, eliminating the need for this annual lift-scrub-and-paint procedure, is now commercially available courtesy of a novel innovation from the company Ecosea.
Copper sheets were used centuries ago to ‘skin’ some of the earliest wooden naval craft, protecting against bio-fouling and also attack by marine borers. Ecosea have homed in on the exceptional and unique properties of one of its alloys, copper-nickel.

At a ratio of 90/10 this alloy displays the optimum resistance to bio-fouling in all water systems, requiring no replacement, usually for the life of the product it protects. In most cases any routine inspection required can be readily performed without lifting.

In the case of fibre-glass hulls and other structures, a matrix of small platelets of the alloy are applied to the underwater areas as self-adhesive sheets approximately 30cm x 36cm, each with enough flexibility to be shaped to the substrate, forming a comprehensive and continuous cladding. Flatter areas can accept plain sheets of copper-nickel (see illustration ). Any small gaps between the platelets and sheets are subsequently filled with a grouting epoxy, which is ‘sqweegeed’ over the fine joints and the excess simply wiped off.

Cuproguard™ is not only suitable for cladding to GRP, it can be used just as easily and effectively on wood, aluminium and steel, hulls and structures.

The performance of the 90/10 alloy as a protective cladding is well established as a result of many years of testing on both pleasure and commercial craft with an amazing success record. Experiments on yachts, ferries, piers and static structures, have shown that bio-fouling control can be simple and effective using copper-nickel. In some cases entire hulls have been constructed in the alloy. The very thin, complex oxide skin that forms when the copper-nickel is submerged gently dissuades attachments in an ecologically compatible manner. After long static exposure a light slime will form, itself containing bio-material. Macro-fouling may occasionally try to colonise too, but will slide off readily, either with natural water movement, or alternatively with a light wipe to clear the surface. Now, with the availability of the product from Ecosea, benefiting from the properties of copper-nickel can be simply achieved via a simple post operation to most new or existing hulls and underwater structures.



RESEARCH & TEST RESULTS
HSE Approval
HSE Approval - HSE 8062
Significant research followed by numerous trials have been conducted on Copper Nickel alloys to confirm the suitability of the material and product for marine use. Before Cuprotect™ could be licensed for use it was necessary to conduct stringent independent trials to ascertain the safety, efficacy and durability of the product.
One such trial was conducted by the UK Government Centre for Environment, Fisheries & Aquaculture Sciences(CEFAS). Six anti-fouling paints (considered to be the most effective anti-foul paints on the market) were compared by CEFAS against Cuprotect™. The tests conducted were to satisfy ISO/DIS 15181-2 to determine the amount of copper and biocide release.
As Cuprotect™ contains no biocides other than oxide film formation it is consequently considered to be very clean. The CEFAS report clearly identifies Cuprotect™ as the most durable and environmentally friendly form of anti-fouling available in the world today.
CEFAS: The Centre for Environment, Fisheries & Aquaculture Sciences (Burnham on Sea) Laboratory, Essex.
Tests were conducted by CEFAS to satisfy the strict controls and regulations laid down by government.Six antifouling paints (considered to be the most effective products on the market) were sent to CEFAS along with Cuproguard™ (tile adhesive version of Cuprotect™) The tests were carried out to satisfy ISO/DIS 15181-2. This determines the amount of copper based release. ISO/DIS 15181-1 determines other biocide release. Cuprotect™ contains no biocides other than oxide film formation, and it's clean. The CEFAS report clearly identifies Cuprotect™ as the most durable and environmentally friendly anti-fouling available in the world today.

SEA TRIALS:
The objective of sea trails was to compare our own practical test results with the CEFAS report at the time of publication. Five test sites were selected for their differing types of seawater, Liverpool Marina, Holyhead Harbour, Fal River, Isle of Scilly and the River Humber.
Liverpool Marina: Quiet, clean mix of fresh and seawater.
Holyhead Harbour: Tidal exposed coastal seawater.
River Fal: Tidal river with some agricultural run-off and pollution.
Isle of Scilly: Archipelago with very clean unpolluted seawaters.
River Humber: Tidal River with some industrial and agricultural pollution.
The test sites were examined after 6 and 7 months, one test buoy in the river Fal was lost. The test buoys showed differing rates of marine fouling on competitor products, only two products were completely free from any growth. The CEFAS report confirmed the actual sea trial results. After 12 months Cuprotect™ was the only sample free of fouling.
RIGOROUS ADHESIVE TESTING:
The tests for Cuprotect™ using our own epoxies are conclusive. In all tests carried out the bond strength of the epoxy adhesive is greater than that of both the cohesive and tensile strengths of GRP/FRP and Concrete. Testing can be carried out on other substrates by request.
These tests apply to Cuproguard™ and Cuprotect™ and are now completed:Shear tests, Tensile tests, Extreme Climatic Conditions (Thermal Shock) tests, Impermeability tests using hydraulic pressure and vacuum tests.

HOW CUPROTECT™ WORKS

Cuprotect™, which is not a paint, is best described as a combination of copper alloys, engineered to conform to the compound curvatures of hulls of sea going yachts and ships, marine structures, under-water pipelines, sea water intakes and indeed, anything that is submerged in water and liaible to bio-fouling.
Cuprotect™ utilises the metallurgical performance of copper alloys in an ingenious combination of several bonded layers that make it easy to apply, very durable, very effective and extremely friendly to the environment as the Cuprotect™ system does not contain any organotins such as TBT's, or volatile organic compounds (VOC's).
The Cuprotect™ system is approximately 350 microns thick and made of granular copper alloys which are bonded into a 'binder coat' of epoxy resin, that contains specially formulated thixotropic agents to ensure a strong and uniform finish. This binder coat is applied to a primer coat of epoxy resin which seals and protects the hull by forming an inpermeable seal.

The unique patented Cuprotect™ system is applied by approved installers only, using specialised computer controlled spray equipment, developed exclusively for Ecosea. This allows application onto compound curved surfaces, such as boat hulls, and by creating an impermeable seal, Cuprotect™also drastically reduces the possibility of osmosis. rust and corrosion.

There is a long, well documented history that confirms the excellent anti-fouling performance and durability of this outstanding alloy. This is mainly due to its durability created by the tough copper nickel oxide film that is formed within hours of immersion and fully matures after 3-4 months. It is this thin but tough Copper Nickel Oxide film that gives Cuprotect™ such a long life expectancy - and a guarantee of 5 years!
Cuprotect™is virtually non-corrodible in clean seawater i.e. natural corrosion is from 1-2 microns per year and even in polluted waters only between 2-12 microns per year, making it perfect as a long term bio-fouling solution not only for yachts and ships, but also to protect offshore platforms, sea water inlets and condensers and underwater pipe work.
When used on the hull of a boat Cuprotect™ becomes active within a period of twelve hours after launching and gains full protection by three months, offering protection for many years against fouling, osmosis, rust and general hull degradation.

PROTECTING AGAINST OSMOSIS/HYDROLYSIS
Yachts are a huge investment in both time and money. The resale value of a yacht with evidence of osmosis can be reduced by at least 30% or as much as 50%, that's if you can find a buyer willing to take it on! Even after professional and expensive osmosis treatment by a competent yard there's no absolute guarantee that it will not reappear. There's only one sure way to prevent osmosis and that is to keep water/water vapour away from the gel coat.

There are many causes of osmosis in boats built in Glass Reinforced Polyester (GRP). The main causes are poor workmanship, bad practice, inferior materials and a general disregard or lack of quality control. All materials used in boat building, particularly those used in the hull need to be of the highest quality. All these hull materials are a compromise and all require maintenance, nothing is maintenance free. Wooden hulls can rot and become infested by marine borers. Steel hulls will eventually rust and corrode away. Ferro Cement hulls can and do suffer from internal degradation caused by rusting strengtheners and mesh. But with GRP hulls the major worry is osmosis, although this doesn't normally cause structural problems it's a financial catastrophe.

The osmosis defence offered by Cuprotect™ is formidable. The barrier of defence consists of a totally impermeable epoxy resin primer coat. a secondary binder coat and a final layer of granulated copper alloy. The complete matrix has been pressure tested to 15 atmospheres, 220 psi, forcing water and air through the matrix. Cuprotect™ was not breached, even under these destructive tests.

There is simply no better protection or defence against osmosis/hydrolysis than that of Cuprotect™ anywhere in the world.

SAFE TO THE ENVIRONMENT
As a responsible manufacturer and provider of environmentally friendly products, systems and services, we at ECOSEA treat the environmental issues earnestly. The company is therefore absolutely committed to the best environmental practices and policies.

There are huge benefits to the environment by using Cuprotect™, compared to polluting anti-fouling paints. Unlike some pain products which contain copper particals suspended within the paint matrix, Cuprotect™ is a solid, engineered product which has 100% active surface open to the marine environment, thereby Cuprotect™does not need regular abrasion to expose the active ingredients.

The cuprous oxide film that develops on Cuprotect™after immersion, not only provides an inhospitable surface to fouling organisms, but effectively seals the Cuprotect™ thereby ensuring leech rates stay significantly below any other copper based products.

The U.K. government expressed a great deal of interest in the development of Cuprotect™ and its predecessor, Cuproguard™, not least due to the potential environmental benefits. After a close examination of the project, by independent experts, U.K. govenment approval was given for full grant aid in November 2000.

Cuprotect™ is the only anti foul product currently available on the market which is safe to the environment yet still very effective at preventing marine bio fouling, as it does not contain any organotins such as TBT, nor volatile organic compounds (VOC's) such as solvents, both of which are found in great quantities in anti-foul paints and both of which are extremely damaging, not only to marine life but also to the ozone layer.




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